| Edition |
10th ed. |
| Description |
xxiv, 1303 pages, 96 unnumbered pages : color illustrations ; 29 cm + 1 study card ([12] pages : color illustrations ; 28 cm) + student access kit |
| Note |
Includes index. |
| Contents |
Machine generated contents note: 1. Matter: Its Properties and Measurement -- 1-1. The Scientific Method -- 1-2. Properties of Matter -- 1-3. Classification of Matter -- 1-4. Measurement of Matter: SI (Metric) Units -- 1-5. Density and Percent Composition: Their Use in Problem Solving -- 1-6. Uncertainties in Scientific Measurements -- 1-7. Significant Figures -- Summary -- Integrative Example -- Exercises -- Integrative and Advanced Exercises -- Feature Problems -- Self-Assessment Exercises -- 2. Atoms and the Atomic Theory -- 2-1. Early Chemical Discoveries and the Atomic Theory -- 2-2. Electrons and Other Discoveries in Atomic Physics -- 2-3. The Nuclear Atom -- 2-4. Chemical Elements -- 2-5. Atomic Mass -- 2-6. Introduction to the Periodic Table -- 2-7. The Concept of the Mole and the Avogadro Constant -- 2-8. Using the Mole Concept in Calculations -- Summary -- Integrative Example -- Exercises -- Integrative and Advanced Exercises -- Feature Problems -- Self-Assessment Exercises. |
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3. Chemical Compounds -- 3-1. Types of Chemical Compounds and Their Formulas -- 3-2. The Mole Concept and Chemical Copmpunds -- 3-3. Composition of Chemical Compounds -- 3-4. Oxidation States: A Useful Tool in Decribing Chemical Compounds -- 3-5. Naming Compounds: Organic and Inorganic Compunds -- 3-6. Names and Formulas of Inorganic Compounds -- 3-7. Names and Formulas of Organic Compunds -- Summary -- Integrative Example -- Exercises -- Integrative and Advanced Exercises -- Feature Problems -- Self-Asessment Exercises -- 4. Chemical Reactions -- 4-1. Chemical Reactions and Chemical Equations -- 4-2. Chemical Equations and Stoichiometry -- 4-3. Chemical Reactions in Solution -- 4-4. Determining the Limiting Reactant -- 4-5. Other Practical Matters in Reaction Stoichiometry -- Summary -- Integrative Example -- Exercises -- Feature Problems -- Self-Assessment Exercises -- 5. Introduction the Reactions in Aqueous Solutions -- 5-1. The Nature of Aqueous Solutions -- 5-2. Precipitation Reactions -- 5-3. Acid-Base Reactions -- 5-4. Oxidation-Reduction Reactions: Some General Principles. |
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7-8. Standard Enthalpies of Formation -- 7-9. Fuels as Sources of Energy -- Summary -- Integrative Example -- Exercises -- Integrative and Advanced Exercises -- Feature Problems -- Self-Assessment Exercises -- 8. Electrons in Atoms -- 8-1. Electromagnetic Radiation -- 8-2. Atomic Spectra -- 8-3. Quantum Theory -- 8-4. The Bohr Atom -- 8-5. Two Ideas Leading to a New Quantum Mechanics -- 8-6. Wave Mechanics -- 8-7. Quantum Numbers and Electron Orbitals -- 8-8. Interpreting and Representing the Orbitals of the Hydrogen Atom -- 8-9. Electron Spin: A Fourth Quantum Number -- 8-10. Multielectron Atoms -- 8-11. Electron Configurations -- 8-12. Electron Configurations and the Periodic Table -- Summary -- Integrative Example -- Exercises -- Integrative and Advanced Exercises -- Feature Problems -- Self-Assessment Exercises -- 9. The Periodic Table and Some Atomic Properties -- 9-1. Classifying the Elements: The Periodic Law and the Periodic Table -- 9-2. Metals and Nonmetals and Their lons -- 9-3. Sizes of Atoms and Ions -- 9-4. Ionization Energy. |
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9-5. Electron Affinity -- 9-6. Magnetic Properties -- 9-7. Periodic Properties of the Elements -- Summary -- Integrative Example -- Exercises -- Integrative and Advanced Exercises -- Feature Problems -- Self-Assessment Exercises -- 10. Chemical Bonding I: Basic Concepts -- 10-1. Lewis Theory: An Overview -- 10-2. Covalent Bonding: An Introduction -- 10-3. Polar Covalent Bonds and Electrostatic Potential Maps -- 10-4. Writing Lewis Structures -- 10-5. Resonance -- 10-6. Exceptions to the Octet Rule -- 10-7. Shapes of Molecules -- 10-8. Bond Order and Bond Lengths -- 10-9. Bond Energies -- Summary -- Integrative Example -- Exercises -- Integrative and Advanced Exercises -- Feature Problems -- Self-Assessment Exercises -- 11. Chemical Bonding II: Additional Aspects -- 11-1. What a Bonding Theory Should Do -- 11-2. Introduction to the Valence-Bond Method -- 11-3. Hybridization of Atomic Orbitals -- 11-4. Multiple Covalent Bonds -- 11-5. Molecular Orbital Theory -- 11-6. Delocalized Electrons: Bonding in the Benzene Molecule. |
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11-7. Bonding in Metals -- 11-8. Some Unresolved Issues: Can Electron Charge-Density Plots Help? -- Summary -- Integrative Example -- Exercises -- Integrative and Advanced Exercises -- Feature Problems -- Self-Assessment Exercises -- 12. Intermolecular Forces: Liquids and Solids -- 12-1. Intermolecular Forces -- 12-2. Some Properties of Liquids -- 12-3. Some Properties of Solids -- 12-4. Phase Diagrams -- 12-5. Network Covalent Solids and Ionic Solids -- 12-6. Crystal Structures -- 12-7. Energy Changes in the Formation of Ionic Crystals -- Summary -- Integrative Example -- Exercises -- Integrative and Advanced Exercises -- Feature Problems -- Self-Assessment Exercises -- 13. Solutions and Their Physical Properties -- 13-1. Types of Solutions: Some Terminology -- 13-2. Solution Concentration -- 13-3. Intermolecular Forces and the Solution Process -- 13-4. Solution Formation and Equilibrium -- 13-5. Solubilities of Gases -- 13-6. Vapor Pressures of Solutions -- 13-7. Osmotic Pressure -- 13-8. Freezing-Point Depression and Boiling-Point Elevation of Nonelectrolyte Solutions. |
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13-9. Solutions of Electrolytes -- 13-10. Colloidal Mixtures -- Summary -- Integrative Example -- Exercises -- Integrative and Advanced Exercises -- Feature Problems -- Self-Assessment Exercises -- 14. Chemical Kinetics -- 14-1. The Rate of a Chemical Reaction -- 14-2. Measuring Reaction Rates -- 14-3. Effect of Concentration on Reaction Rates: The Rate Law -- 14-4. Zero-Order Reactions -- 14-5. First-Order Reactions -- 14-6. Second-Order Reactions -- 14-7. Reaction Kinetics: A Summary -- 14-8. Theoretical Models for Chemical Kinetics -- 14-9. The Effect of Temperature on Reaction Rates -- 14-10. Reaction Mechanisms -- 14-11. Catalysis -- Summary -- Integrative Example -- Exercises -- Integrative and Advanced Exercises -- Feature Problems -- Self-Assessment Exercises -- 15. Principles of Chemical Equilibrium -- 15-1. Dynamic Equilibrium -- 15-2. The Equilibrium Constant Expression -- 15-3. Relationships Involving Equilibrium Constant -- 15-4. The Magnitude of an Equilibrium Constant -- 15-5. The Reaction Quotient, Q: Predicting the Direction of Net Change -- 15-6. Altering Equilibrium Conditions: Le Chatelier's Principle. |
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15-7. Equilibrium Calculations: Some Illustrative Examples -- Summary -- Integrative Example -- Exercises -- Integrative and Advanced Exercises -- Feature Problems -- Self-Assessment Exercises -- 16. Acids and Bases -- 16-1. Arrhenius Theory: A Brief Review -- 16-2. Brønsted-Lowry Theory of Acids and Bases -- 16-3. Self-Ionization of Water and the pH Scale -- 16-4. Strong Acids and Strong Bases -- 16-5. Weak Acids and Weak Bases -- 16-6. Polyprotic Acids -- 16-7. Ions as Acids and Bases -- 16-8. Molecular Structure and Acid-Base Behavior -- 16-9. Lewis Acids and Bases -- Summary -- Integrative Example -- Exercises -- Integrative and Advanced Exercises -- Feature Problems -- Self-Assessment Exercises -- 17. Additional Aspects of Acid-Base Equilibria -- 17-1. Common-Ion Effect in Acid-Base Equilibria -- 17-2. Buffer Solutions -- 17-3. Acid-Base Indicators -- 17-4. Neutralization Reactions and Titration Curves -- 17-5. Solutions of Salts of Polyprotic Acids -- 17-6. Acid-Base Equilibrium Calculations: A Summary -- Summary -- Integrative Example -- Exercises -- Integrative and Advanced Exercises -- Feature Problems -- Self-Assessment Exercises. |
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18. Solubility and Complex-Ion Equilibria -- 18-1. Solubility Product Constant, Ksp -- 18-2. Relationship Between Solubility and Ksp -- 18-3. Common-Ion Effect in Solubility Equilibria -- 18-4. Limitations of the Ksp Concept -- 18-5. Criteria for Precipitation and Its' Comleteness -- 18-6. Fractional Precipitation -- 18-7. Solubility and pH -- 18-8. Equilibria Involving Complex Ions -- 18-9. Qualitative Cation Analysis -- Summary -- Integrative Example -- Exercises -- Integrative and Advanced Exercises -- Feature Problems -- Self-Assessment Exercises. |
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20-6. Corrosion: Unwanted Voltaic Cell -- 20-7. Electrolysis: Causing Nonspontaneous Reactions to Occur -- 20-8. Industrial Electrolysis Processes -- Summary -- Integrative Example -- Exercises -- Integrative and Advanced Exercises -- Feature Problems -- Self-Assessment Exercises -- 21. Chemistry of the Main-Group Elements I: Groups 1, 2, 13, and 14 -- 21-1. Periodic Trends and Charge Density -- 21-2. Group 1: The Alkali Metals -- 21-3. Group 2: The Alkaline Earth Metals -- 21-4. Group 13: The Boron Family -- 21-5. Group 14: The Carbon Family -- Summary -- Integrative Example -- Exercises -- Integrative and Advanced Exercises -- Feature Problems -- Self-Assessment Exercises -- 22. Chemistry of the Main-Group Elements II: Groups 18, 17, 16, 15, and Hydrogen -- 22-1. Periodic Trends in Bonding -- 22-2. Group 18: The Noble Gases -- 22-3. Group 17: The Halogens -- 22-4. Group 16: The Oxygen Family. |
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22-5. Group 15: The Nitrogen Family -- 22-6. Hydrogen: A Unique Element -- Summary -- Integrative Example -- Exercises -- Integrative and Advanced Exercises -- Feature Problems -- Self-Assessment Exercises -- 23. The Transition Elements -- 23-1. General Properties -- 23-2. Principles of Extractive Metallurgy -- 23-3. Metallurgy of Iron and Steel -- 23-4. First-Row Transition Metal Elements: Scandium to Manganese -- 23-5. The Iron Triad: Iron, Cobalt, and Nickel -- 23-6. Grup 11: Copper, Silver, and Gold -- 23-7. Group 12: Zinc, Cadmium, and Mercury -- 23-8. Lanthanides -- 23-9. High-Temperature Superconductors -- Summary -- Integrative Example -- Exercises -- Integrative and Advanced Exercises -- Feature Problems -- Self-Assessment Exercises -- 24. Complex Ions and Coordination Compounds -- 24-1. Werner's Theory of Coordination Compounds: An Overview -- 24-2. Ligands -- 24-3. Nomenclature. |
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24-4. Isomerism -- 24-5. Bonding in Complex Ions: Crystal Field Theory -- 24-6. Magnetic Properties of Coordination Compounds and Crystal Field Theory -- 24-7. Color and the Colors of Complexes -- 24-8. Aspects of Complex-Ion Equilibria -- 24-9. Acid-Base Reactions of Complex Ions -- 24-10. Some Kinetic Considerations -- 24-11. Applications of Coordination Chemistry -- Summary -- Integrative Example -- Exercises -- Integrative and Advanced Exercises -- Feature Problems -- Self-Assessment Exercises -- 25. Nuclear Chemistry -- 25-1. Radioactivity -- 25-2. Naturally Occuring Radioactive Isotopes -- 25-3. Nuclear Reactions and Artificially Induced Radioactivity -- 25-4. Transuranium Elements -- 25-5. Rate of Radioactive Decay -- 25-6. Energetics of Nuclear Reactions -- 25-7. Nuclear Stability -- 25-8. Nuclear Fission -- 25-9. Nuclear Fusion -- 25-10. Effect of Radiation on Matter. |
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25-11. Applications of Radioisotopes -- Summary -- Integrative Example -- Exercises -- Integrative and Advanced Exercises -- Feature Problems -- Self-Assessment Exercises -- 26. Structures of Organic Compounds -- 26-1. Organic Compounds and Structures: An Overview -- 26-2. Alkanes -- 26-3. Cycloalkanes -- 26-4. Stereoisomerism in Organic compounds -- 26-5. Alkenes and Alkynes -- 26-6. Aromatic Hydrocarbons -- 26-7. Organic Compound Containing Functional Groups -- 26-8. From Molecular Formula to Molecular Structure -- Summary -- Integrative Example -- Exercises -- Integrative and Advanced Exercises -- Feature Problem -- Self-Assessment Exercises -- 27. Reactions of Organic Compounds -- 27-1. Organic Reactions: An Introduction -- 27-2. Introduction to Nucleophilic Substitution Reactions -- 27-3. Introduction to Elimination Reactions -- 27-4. Reactions of Alcohols -- 27-5. Introduction to Addition Reactions: Reactions of Alkenes. |
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27-6. Electrophilic Aromatic Substitution -- 27-7. Reactions of Alkanes -- 27-8. Polymers and Polymerization Reactions -- 27-9. Synthesis of Organic Compounds -- Summary -- Integrative Example -- Exercises -- Integrative and Advanced Exercises -- Feature Problem -- Self-Assessment Exercises -- 28. Chemistry of the Living State -- 28-1. Chemical Structure of Living Matter: An Overview -- 28-2. Lipids -- 28-3. Carbohydrates -- 28-4. Proteins -- 28-5. Aspects of Metabolism -- 28-6. Nucleic Acids -- Summary -- Integrative Example -- Exercises -- Integrative and Advanced Exercises -- Feature Problems -- Self-Assessment Exercises -- Appendices -- A. Mathematical Operations -- B. Some Basic Physical Concepts -- C. SI Units -- D. Data Tables -- E. Concept Maps -- F. Glossary -- G. Answers to Concept Assessment Questions. |
| Summary |
The Molecule on the Front Cover is Paclitaxel, C47H51NO14 a chemotherapy drug that has been successful in treating breast, lung, and ovatian cancer. It is extracted from the bark of the Pacific Yew tree (Taxus brevifolia). Unfortunately, the bark of a 100-year-old Pacific Yew tree yields about 3 kg of bark and only 300 mg of paclitaxel, barely enough for a single dose of the drug (Taxol). |
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The synthesis of this molecule engaged the attention of chemists for more than 20 years until finally, in 1994, chemists from Florida State University and from the University of California (San Diego) announced independently that they were able to synthesize it from simpler and readily available starting materials. A major challenge in the synthesis of paclitaxel is getting the spatial arrangement of atoms around 11 of the carbon atoms just right. These 11 carbon atoms are identified in the ball-and-stick structure by green or purple circles. If the synthesis is not done carefully, up to 2048 different possible paclitaxel-like structures could be obtained, but only one is known to have the desired anti-tumor activity. Because chemists can now synthesize paclitaxel, it is possible for researchers to explore how it works and design new chemotherapeutic drugs that are safer and more effective. --Book Jacket. |
| Subject |
Chemistry.
|
|
Chemistry -- Problems, exercises, etc.
|
|
Chemistry. (OCoLC)fst00853344
|
|
Kemi.
|
| Genre/Form |
Problems and exercises. (OCoLC)fst01423783
|
| Added Author |
Petrucci, Ralph H.
|
| ISBN |
9780136121497 (hardback) |
|
0136121497 (hardback) |
|
9780137032105 (Mastering chemistry ; student access kit) |
|
0137032102 (Mastering chemistry ; student access kit) |
|
0137032129 (study card) |
|
9780137032129 (study card) |
|
9780132064521 |
|
0132064529 |
